Cyclohexanone, 2-hydroxy- → 3-Methyl-4,6,7,8-tetrahydro-2(3H)-naphthalenone

HRID 478073

반응식

HRID 478073 반응식
O[CH:2]1[CH2:7][CH2:6][CH2:5][CH2:4][C:3]1=O.CC1C(=O)CCCC=1C.[CH3:18][CH2:19][C:20](=[O:23])[CH:21]=[CH2:22].[OH-].[K+].[Li+].CC([N-]C(C)C)C>CO.C1COCC1>[CH3:22][CH:21]1[CH2:6][C:7]2[C:18]([CH2:5][CH2:4][CH2:3][CH:2]=2)=[CH:19][C:20]1=[O:23]

참가 물질

8

반응물 5

HCID 10785Cyclohexanone, 2-hydroxy-HCID 14797Potassium HydroxideHCID 153941-Penten-3-oneHCID 2724682Lithium diisopropylamideHCID 108878982,3-Dimethyl-2-cyclohexen-1-one

생성물 1

HCID 109098813-Methyl-4,6,7,8-tetrahydro-2(3H)-naphthalenone

시약·촉매·용매 2

HCID 887Methanol용매HCID 8028Tetrahydrofuran용매

실험 절차

This material is prepared according to the procedure for Preparation 5 wherein 2-hydroxycyclohexanone is substituted for 2,3-dimethylcyclohexenone, methylbutenone is substituted for MVK, and 2N KOH in MeOH is substituted fro LDA in THF.

후처리

  1. customThis material is prepared

출처 및 근거

ORD 기록
ord-ace3d167981649f5b92a1c86044c0fb5
출처 데이터셋
uspto-grants-1989_12
특허 번호
US04889947

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