Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzyl Bromide → 2-(Benzyloxy)-6-bromonaphthalene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzyl Bromide | HCID 7498 | — |
| 반응물 | 6-Bromo-2-naphthalenol | HCID 27144 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 용매 | Cesium carbonate | HCID 10796 | — |
| 생성물 | 2-(Benzyloxy)-6-bromonaphthalene | HCID 640595 | — |
반응 단계
To the commercially available 6-bromo-naphthalene-2-ol (1) (1 equi.) and benzyl bromide (2) (1 equi.) in DMF (3mL/mmole), cesium carbonate (1.25 equi.) was added at room temperature. The reaction mixture was stirred at that temperature for 24 h, quenched with water, extracted with ethyl acetate:hexane (1:1), washed with brine, over MgSO4, and concentrated in vacuo.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06703082B1 |
| 출처 데이터셋 | uspto-grants-2004_03 |
| ORD ID | ord-2d89c4a6c19742cea11d66a9ead29487 |
| 출처 메모 | uspto-grants-2004_03 |