Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Iodide → 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-[4-(3,7-dimethyloctyloxy)phenyl]-fluorene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Iodide | HCID 5238 | — |
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 반응물 | 1-Chloro-3,7-dimethyloctane | HCID 227360 | — |
| 반응물 | 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-(4-hydroxyphenyl)fluorene | HCID 18766847 | — |
| 용매 | Ethanol | HCID 702 | — |
| 용매 | Ethyl Acetate | HCID 8857 | — |
| 생성물 | 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-[4-(3,7-dimethyloctyloxy)phenyl]-fluorene | HCID 18766842 | — |
반응 단계
52 g of 2,7-dibromo-9-(2,5-dimethylphenyl)-9-(4-hydroxyphenyl)fluorene were refluxed with 18 g of 3,7-dimethyloctyl chloride, 80 ml of ethanol, 7 g of KOH and 1 g of NaI for 5 days. According to TLC, the reaction was complete after this time. The solvent was stripped off, ethyl acetate was added, and the precipitate was filtered off with suction and rinsed a number of times with ethyl acetate. The organic phase was dried, and the solvent was stripped off.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06653438B1 |
| 출처 데이터셋 | uspto-grants-2003_11 |
| ORD ID | ord-6d04b460c8404279aa774d3bf11f9768 |
| 출처 메모 | uspto-grants-2003_11 |