Glyceric acid → Solketal
반응식
[C:1]([OH:7])(=O)[CH:2]([CH2:4][OH:5])[OH:3].CO[C:10](OC)([CH3:12])[CH3:11].C(O)[C@H](O)C(O)=O.[H-].[Al+3].[Li+].[H-].[H-].[H-]>CO>[CH3:11][C:10]1([CH3:12])[O:3][CH:2]([CH2:4][OH:5])[CH2:1][O:7]1참가 물질
6
실험 절차
Alternatively, the glyceric acid can be reacted with the 2,2-dimethoxypropane without methanol to prepare 2,3-O-isopropylidene D- or L-glyceric acid which is then reacted with lithium aluminum hydride to produce the solketal.
출처 및 근거
- ORD 기록
- ord-12372ba251834ee4b61c179f32962dcb
- 출처 데이터셋
- uspto-grants-1986_03
- 특허 번호
- US04575558
반응 노트
불러오는 중…