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Water → p-n-Tetradecyloxy-4-(2-methylbutoxycarbonyl)benzylideneaniline

HRID 482818
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인쇄 미리보기

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HRID 482818 반응식
[CH3:1][CH:2]([CH2:15][CH3:16])[CH2:3][O:4][C:5]([C:7]1[CH:14]=[CH:13][C:10]([CH:11]=O)=[CH:9][CH:8]=1)=[O:6].[CH2:17]([O:31][C:32]1[CH:38]=[CH:37][C:35]([NH2:36])=[CH:34][CH:33]=1)[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30].C1(C)C=CC(S(O)(=O)=O)=CC=1.O>C1(C)C=CC=CC=1>[CH2:17]([O:31][C:32]1[CH:38]=[CH:37][C:35]([N:36]=[CH:11][C:10]2[CH:13]=[CH:14][C:7]([C:5]([O:4][CH2:3][CH:2]([CH3:1])[CH2:15][CH3:16])=[O:6])=[CH:8][CH:9]=2)=[CH:34][CH:33]=1)[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 4

HCID 962WaterHCID 6101p-Toluenesulfonic acidHCID 191002p-(n-Tetradecyloxy)phenylamineHCID 13548338p-(2-Methylbutoxycarbonyl)benzaldehyde

생성물 1

HCID 13628479p-n-Tetradecyloxy-4-(2-methylbutoxycarbonyl)benzylideneaniline

시약·촉매·용매 1

HCID 1140Toluene
용매

실험 절차

44.3 g of said p-(2-methylbutoxycarbonyl)benzaldehyde, 32 g of p-n-tetradecyloxyaniline, and 0.1 g of p-toluenesulfonic acid were dissolved in toluene. The solution was heated under reflux, and water generated in the dehydrating condensation was removed with a Dean-Stark condenser. After the reaction solution was cooled, the organic layer was washed with water, and the solvent (toluene) was distilled off in vacuum. The solid residue was recrystallized from ethanol to obtain yellow crystals.

후처리

  1. temperatureThe solution was heated
  2. temperatureunder reflux
  3. customwas removed with a Dean-Stark condenser
  4. temperatureAfter the reaction solution was cooled
  5. washthe organic layer was washed with water
  6. distillationthe solvent (toluene) was distilled off in vacuum
  7. customThe solid residue was recrystallized from ethanol
  8. customto obtain yellow crystals

출처 및 근거

ORD 기록
ord-063c506506db4d19beb5dc80ac421b83
출처 데이터셋
uspto-grants-1986_03
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04576732

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