Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2-Chloro-4-nitropyridine 1-oxide → Pyridine, 2-chloro-4-methoxy-, 1-oxide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2-Chloro-4-nitropyridine 1-oxide | HCID 84433 | — |
| 반응물 | Sodium | HCID 5360545 | — |
| 반응물 | Sodium Methoxide | HCID 10942334 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | Pyridine, 2-chloro-4-methoxy-, 1-oxide | HCID 15593755 | — |
반응 단계
Sodium (0.46 g) is dissolved in absolute methanol (50 ml) and the resultant solution of sodium methoxide is added to a solution of 2-chloro-4-nitropyridine-1-oxide (3.5 g, prepared as described in Example 1) in methanol (10 ml). The reaction mixture is allowed to stand at room temperature for 50 hours and is then subjected to rotary evaporation to give 2-chloro-4-methoxypyridine-1-oxide.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | USRE034313 |
| 출처 데이터셋 | uspto-grants-1993_07 |
| ORD ID | ord-20eeab3c45f14020a6979e4c216e0572 |
| 출처 메모 | uspto-grants-1993_07 |