Perfluoropropionyl fluoride → 1,1,1,3,3,4,4,4-Octafluoro-2-(trifluoromethyl)-2-butanol

HRID 483915

반응식

HRID 483915 반응식
[F-:1].[K+].[F:3][C:4]([F:12])([C:8]([F:11])([F:10])[F:9])[C:5](F)=[O:6]>C(#N)C>[F:1][C:4]([F:12])([F:3])[C:5]([C:8]([F:11])([F:10])[F:9])([OH:6])[C:4]([F:12])([F:3])[C:8]([F:11])([F:10])[F:9]

참가 물질

4

반응물 2

HCID 67912Perfluoropropionyl fluorideHCID 522689Potassium Fluoride

생성물 1

HCID 1608131,1,1,3,3,4,4,4-Octafluoro-2-(trifluoromethyl)-2-butanol

시약·촉매·용매 1

HCID 6342Acetonitrile용매

반응 조건

온도
-196 °C

실험 절차

By operating as in the above examples, 0.26 g of KF (4.5 mmol) was charged to the reactor, and then 4.0 ml of anhydrous acetonitrile was injected through the pierceable cap; the whole was then cooled down to -196° C. with the residual air being evacuated; then, 2.0 mmol of pentafluoropropionyl fluoride

후처리

  1. additionwas charged to the reactor
  2. custombeing evacuated

출처 및 근거

ORD 기록
ord-26b6efaca80344a497d3f837a6d8c214
출처 데이터셋
uspto-grants-1993_07
특허 번호
US05227539

연결된 노트

불러오는 중…