Toluene → Cobalt (II) acetylacetonate
반응식
[CH3:1]/[C:2](/[OH:7])=[CH:3]/[C:4]([CH3:6])=[O:5].[CH3:8]/[C:9](/[OH:14])=[CH:10]/[C:11]([CH3:13])=[O:12].O.[Co:16].C1(C)C=CC=CC=1>O>[CH3:1]/[C:2](/[OH:7])=[CH:3]\[C:4]([CH3:6])=[O:5].[CH3:8]/[C:9](/[OH:14])=[CH:10]/[C:11]([CH3:13])=[O:12].[Co:16]참가 물질
4
실험 절차
Cobalt(II) acetylacetonate in essentially anhydrous form was first produced from commercially available cobalt(II) acetylacetonate hydrate. A suspension of the cobalt(II) acetylacetonate hydrate (about 10 g) and toluene (200 mL) was heated to reflux under nitrogen atmosphere with agitation for 24 hours. Water was accordingly refluxed into a Dean-Stark trap. The resulting mixture was then filtered in a nitrogen atmosphere and dried in vacuo for a period of between 1 and 2 hours to give the anhydrous cobalt(II) acetylacetonate.
후처리
- temperaturewas heated
- temperatureto reflux under nitrogen atmosphere with agitation for 24 hours
- filtrationThe resulting mixture was then filtered in a nitrogen atmosphere
- customdried in vacuo for a period of between 1 and 2 hours
출처 및 근거
- ORD 기록
- ord-a356522ca6b9436390784435303582de
- 출처 데이터셋
- uspto-grants-1993_07
- 특허 번호
- US05227562
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