Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethyl 2-(diethoxyphosphoryl)butanoate → Ethyl 5,9-dimethyl-2-ethyl-11-(2,6,6-trimethyl-1cyclohexen-1-yl)-2,4,6,8,10-undecapentaenoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethyl 2-(diethoxyphosphoryl)butanoate | HCID 229053 | — |
| 반응물 | Retinal | HCID 638015 | — |
| 생성물 | Ethyl 5,9-dimethyl-2-ethyl-11-(2,6,6-trimethyl-1cyclohexen-1-yl)-2,4,6,8,10-undecapentaenoate | HCID 54016105 | — |
반응 단계
In analogy to the procedure given in Example 1: Triethyl 2-phosphonobutyrate was reacted with retinal to give ethyl 5,9-dimethyl-2-ethyl-11-(2,6,6-trimethyl-1cyclohexen-1-yl)-2,4,6,8,10-undecapentaenoate, which was converted by the procedure of Example 2 to 5,9-dimethyl-2-ethyl-11-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4,6,8,10-undecapentaenoic acid, m.p.=164°-165° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04534979 |
| 출처 데이터셋 | uspto-grants-1985_08 |
| ORD ID | ord-f9a2e73f8b854d11b49ef04a9c706c84 |
| 출처 메모 | uspto-grants-1985_08 |