Butylamine → 3-(n-Butyliminomethyl)dibenzo[b,f]thiepin-5,5-dioxide

HRID 485109노트

반응식

HRID 485109 반응식
[CH:1]1[C:11]2[CH:10]=[CH:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6](=[O:17])(=[O:16])[C:5]=2[CH:4]=[C:3]([CH:18]=O)[CH:2]=1.[CH2:20]([NH2:24])[CH2:21][CH2:22][CH3:23]>C1C=CC=CC=1>[CH2:20]([N:24]=[CH:18][C:3]1[CH:2]=[CH:1][C:11]2[CH:10]=[CH:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6](=[O:17])(=[O:16])[C:5]=2[CH:4]=1)[CH2:21][CH2:22][CH3:23]

참가 물질

4

반응물 2

HCID 8007ButylamineHCID 13520245Dibenzo[b,f]thiepin-3-carboxaldehyde 5,5-dioxide

생성물 1

HCID 202715033-(n-Butyliminomethyl)dibenzo[b,f]thiepin-5,5-dioxide

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

Reflux a mixture of 200 mg of dibenzo[b,f]thiepin-3-carboxaldehyde-5,5-dioxide (0.74 mmole) and 82 mg of n-butylamine (1.11 mmole) in 0.30 ml of benzene, with azetropic removal of water, for 45 minutes. Evaporate the mixture to remove the benzene and excess butylamine and obtain the title product as an oil.

후처리

  1. temperatureReflux
  2. customwith azetropic removal of water
  3. customEvaporate the mixture
  4. customto remove the benzene and excess butylamine

출처 및 근거

ORD 기록
ord-d7aac1ce47c146cd9f4b83a8e1c8625f
출처 데이터셋
uspto-grants-1985_08
특허 번호
US04535171

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