Sodium Propionate → HCID 13335395, 화합물
반응식
C(O[C:5]1([CH3:14])[CH:9]=[CH:8][C:7](=[O:10])[CH:6]1[CH2:11][CH:12]=[CH2:13])(=O)C.[C:15]([O-:19])(=[O:18])[CH2:16][CH3:17].[Na+]>C(O)(=O)CC>[CH2:11]([C:6]1[C:7](=[O:10])[CH2:8][CH:9]([O:19][C:15](=[O:18])[CH2:16][CH3:17])[C:5]=1[CH3:14])[CH:12]=[CH2:13]참가 물질
4
실험 절차
In the same apparatus as in Example 1, 3-acetoxy-2-allyl-3-methyl-4-cyclopentenone (19.4 g), propionic acid (70 ml) and sodium propionate (5 g) were charged and agitated at 110° to 120° C. for 6 hours. After the completion of the reaction, propionic acid was evaporated off under reduced pressure. The residue was extracted with toluene (70 ml) and water (40 ml) and treated as in Example 1 to obtain 2-allyl-4-propionyloxy-3-methyl-2-cyclopentenone (16.1 g). Yield, 83%. B.P., 115°-120° C./0.1-0.2 mmHg.
후처리
- customwas evaporated off under reduced pressure
- extractionThe residue was extracted with toluene (70 ml) and water (40 ml)
- additiontreated as in Example 1
출처 및 근거
- ORD 기록
- ord-a427c184c5cd471eb62c1d508192db79
- 출처 데이터셋
- uspto-grants-1985_08
- 특허 번호
- US04535182
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