참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Hydrochloric Acid | HCID 313 | — |
| 반응물 | Hexachloroethane | HCID 6214 | — |
| 반응물 | Dicyclohexylphosphine | HCID 13239 | — |
| 생성물 | Chlorodicyclohexylphosphine | HCID 2734135 | 58.9% |
반응 단계
19.8 g (0.1 mol) dicyclohexylphosphane was added dropwise at room temperature to 26.1 g (0.11 mol) hexachloroethane. After the exothermal reaction which took place with evolution of HCl was terminated, the reaction mixture was stirred for 3 hours at 100° C. The yields (31 -P-NMR) were as follows: δ P=125.2 ((C6H11)2PCl, 94 wgt %); δ P=194.4 (C6H11PCl2, 2 wgt %); δ P=76.7 ((C6H11)2P(O)Cl, 4 wgt %). The crude product was distilled and 13.7 g (59 wgt %) dicyclohexylchlorophosphane (bp.: 136°-138° C./4 millibars) was obtained.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US04536350 |
|---|
| 출처 데이터셋 | uspto-grants-1985_08 |
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| ORD ID | ord-484804a6c0c94b3ea6e8b39d334ae63c |
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| 출처 메모 | uspto-grants-1985_08 |
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