Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Trimethyl phosphite → Phosphinecarboxylic acid, dimethoxy-, 4-methylphenyl ester, oxide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Trimethyl phosphite | HCID 8472 | — |
| 반응물 | p-Tolyl chloroformate | HCID 70304 | — |
| 생성물 | Phosphinecarboxylic acid, dimethoxy-, 4-methylphenyl ester, oxide | HCID 512116 | 93% |
반응 단계
From 10.3 g (85 mmole) of trimethylphosphite and 10.3 g (60 mmole) of p-tolyl chloroformate (prepared according to M. J. Zabik and R. D. Scheutz J. Org. Chem. 32 (1967) 300). (100°, 2 hours) yield 93%. B.p.0.2 131°, nD20 1.4972. Analysis for C10H13O5P. Found (calculated): C 49.37 (49.18). H 5.53 (5.36), P 11.71 (12.69). NMR (CDCl3)δ: 2.40 (CH3), 3.92 and 4.12 (CH3O), 6.97-7.37 (aromatic protons).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04536400 |
| 출처 데이터셋 | uspto-grants-1985_08 |
| ORD ID | ord-a5b71eb669654b8d9f6cf8edc9c6ffd3 |
| 출처 메모 | uspto-grants-1985_08 |