Trifluoroacetate → Bis(4-isopropylphenyl)iodosyl trifluoroacetate

HRID 485628노트

반응식

HRID 485628 반응식
[CH:1]([C:4]1[CH:9]=[CH:8][C:7]([I:10](=[O:12])=[O:11])=[CH:6][CH:5]=1)([CH3:3])[CH3:2].[F:13][C:14]([F:19])([F:18])[C:15]([O-])=[O:16].F[P-](F)(F)(F)(F)F.[K+]>O>[F:13][C:14]([F:19])([F:18])[C:15]([O:11][I:10]([C:7]1[CH:8]=[CH:9][C:4]([CH:1]([CH3:3])[CH3:2])=[CH:5][CH:6]=1)([C:7]1[CH:8]=[CH:9][C:4]([CH:1]([CH3:3])[CH3:2])=[CH:5][CH:6]=1)=[O:12])=[O:16]

참가 물질

5

반응물 3

HCID 84468TrifluoroacetateHCID 23688904Potassium hexafluorophosphateHCID 867402694-Isopropyliodoxybenzene

생성물 1

HCID 20268910Bis(4-isopropylphenyl)iodosyl trifluoroacetate

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

Bis(4-isopropylphenyl)iodosyl trifluoroacetate is prepared by a similar method to that described by F. M. Beringer and P. Boedlander, loc. cit.) using 4-isopropyliodoxybenzene (8.3 g) as starting material. The trifluoroacetate is dissolved in boiling water. Potassium hexafluorophosphate (2 molar excess) in water is added and the solution is allowed to cool. The crystals which form are collected by filtration and dried in air to afford bis(4-isopropylphenyl)iodosyl hexafluorophosphate (0.4 g) m.pt. 84° C. Spectroscopic analysis shows:

후처리

  1. temperatureto cool
  2. filtrationThe crystals which form are collected by filtration
  3. customdried in air

출처 및 근거

ORD 기록
ord-7afbdc6c5a68453297dfdf3b7c237c50
출처 데이터셋
uspto-grants-1985_08
특허 번호
US04537725

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