Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
O-Xylene → Benzene, m-dibutyl-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | O-Xylene | HCID 7237 | — |
| 반응물 | 1,3-Dichlorobenzene | HCID 10943 | — |
| 반응물 | HCID 178418265 | HCID 178418265 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | Butylbenzene | HCID 7705 | — |
| 생성물 | Benzene, m-dibutyl- | HCID 204985 | 23% |
반응 단계
To 2.00 g (13.60 mmole) of m-dichlorobenzene, 0.050 g (0.065 mmoles) of [NitriphosCl]PF6 in 20 mL of ether at -78° C. was added 7.0 mL (14.0 mmoles) of 2M nBuMgCl in ether. The mixture was refluxed for 2 hrs. Then, 0.841 g of o-xylene was added as an internal standard and GC analysis on Column A (70° C. (0 min), 16°/min to 220° C.) yielded 68% of 1-chloro, 3-n-butylbenzene and 23% of 1,3-di-n-butylbenzene which was confirmed by GC/MS.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04538003 |
| 출처 데이터셋 | uspto-grants-1985_08 |
| ORD ID | ord-870714dc29ef48c780a280adc99835f8 |
| 출처 메모 | uspto-grants-1985_08 |