2,3-Dimethyl-2-butene → Dimethyl 2,2,3,3-tetramethylcyclopropanedicarboxylate

HRID 487028

반응식

HRID 487028 반응식
[N+](=[C:3]([C:8]([O:10][CH3:11])=[O:9])[C:4]([O:6][CH3:7])=[O:5])=[N-].[CH3:12][C:13](=[C:15]([CH3:17])[CH3:16])[CH3:14]>[Hg]>[CH3:12][C:13]1([CH3:14])[C:15]([CH3:17])([CH3:16])[C:3]1([C:8]([O:10][CH3:11])=[O:9])[C:4]([O:6][CH3:7])=[O:5]

참가 물질

4

반응물 2

HCID 112502,3-Dimethyl-2-buteneHCID 5476732-Diazonio-1,3-dimethoxy-3-oxoprop-1-en-1-olate

생성물 1

HCID 13415962Dimethyl 2,2,3,3-tetramethylcyclopropanedicarboxylate수율 30.8%

시약·촉매·용매 1

HCID 23931Mercury촉매

실험 절차

A mixture of 20.0 grams (0.13 mole) of dimethyl diazomalonate and 164.35 grams (1.95 moles) of 2,3-dimethyl-2-butene was photolyzed at room temperature for a period of approximately 47 hours in the presence of a 100-watt Hanovia mercury lamp. Most of the unreacted 2,3-dimethyl-2-butene was removed by distillation, at atmospheric pressure, to a head temperature of 73° C. and the still residue was subjected to flash chromatography on a silica gel column to give 9.00 grams (0.04 mole) of dimethyl 2,2,3,3-tetramethylcyclopropanedicarboxylate. NMR analysis of the product indicated the following:

후처리

  1. customMost of the unreacted 2,3-dimethyl-2-butene was removed by distillation, at atmospheric pressure, to a head temperature of 73° C.

출처 및 근거

ORD 기록
ord-00b6f8f1372f4d36a710da393e7c716f
출처 데이터셋
uspto-grants-1994_03
특허 번호
US05292937

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