Isophthalic Acid → Barium(2+);benzene-1,3-dicarboxylate

HRID 487710

반응식

HRID 487710 반응식
[C:1]([OH:12])(=[O:11])[C:2]1[CH:10]=[CH:9][CH:8]=[C:4]([C:5]([OH:7])=[O:6])[CH:3]=1.O.[OH-].[Ba+2:15].[OH-]>O>[C:1]([O-:12])(=[O:11])[C:2]1[CH:10]=[CH:9][CH:8]=[C:4]([C:5]([O-:7])=[O:6])[CH:3]=1.[Ba+2:15]

참가 물질

4

반응물 2

HCID 8496Isophthalic AcidHCID 17749100Barium hydroxide, monohydrate

생성물 1

HCID 22993049Barium(2+);benzene-1,3-dicarboxylate

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
90 °C

실험 절차

100 gms of isophthalic acid (0.6 mole) was slurried in 1 liter of water, the mixture heated to 90° C. and an equivalent amount of barium hydroxide monohydrate was added over a 25 minute period. The reaction mixture was kept at 90°-95° C. for an additional 45 minutes and allowed to cool at room temperature. Barium isophthalate was obtained in the form of long rods (with a length greater than 200 microns) and aspect ratios above 10. Anhydrous rods are produced by heating to dehydrate in a manner similar to the above examples.

후처리

  1. temperatureto cool at room temperature

출처 및 근거

ORD 기록
ord-f524ceab64b747f2ba27542ab9883fdb
출처 데이터셋
uspto-grants-1994_03
특허 번호
US05296585

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