Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Chloro-2-(trifluoromethyl)benzene → HCID 532426, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Chloro-2-(trifluoromethyl)benzene | HCID 6921 | — |
| 반응물 | 4-Methoxyphenol | HCID 9015 | — |
| 반응물 | Sodium Carbonate | HCID 10340 | — |
| 반응물 | 1,4-Bis(diphenylphosphino)butane | HCID 82124 | — |
| 반응물 | HCID 178418416 | HCID 178418416 | — |
| 촉매 | Palladium Chloride | HCID 24290 | — |
| 생성물 | HCID 532426 | HCID 532426 | — |
반응 단계
In an autoclave made of a metal were placed 45.13 g of ortho-chlorobenzotrifluoride, 6.2 g of para-methoxyphenol, 88.5 mg of palladium chloride, 213 mg of 1,4-bisdiphenylphosphinobutane and 5.3 g of sodium carbonate. The air in the autoclave was replaced with carbon monoxide introduced thereinto in several times, after which carbon monoxide was further introduced to adjust its pressure therein to 30 kg/cm2. The internal temperature was adjusted to 190° C. on a salt bath and the reaction was carried out thereon with stirring for 5 hours.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05296601 |
| 출처 데이터셋 | uspto-grants-1994_03 |
| ORD ID | ord-d55c1ac288e24512823a757050b66de0 |
| 출처 메모 | uspto-grants-1994_03 |