Methyl 3-oxo-7,11,15-trimethylhexadeca-6,10,14-trienoate → [2-Hydroxy-6,10,14-trimethylpentadeca-5,9,13-trienyl]phosphonic acid

HRID 488153

반응식

HRID 488153 반응식
O=C(CCC=C(C)CCC=C(C)CCC=C(C)C)CC(OC)=O.[O:24]=[C:25]([CH2:33][CH2:34][CH:35]=[C:36]([CH3:48])[CH2:37][CH2:38][CH:39]=[C:40]([CH3:47])[CH2:41][CH2:42][CH:43]=[C:44]([CH3:46])[CH3:45])[CH2:26][P:27](=[O:32])([O:30]C)[O:28]C>>[OH:24][CH:25]([CH2:33][CH2:34][CH:35]=[C:36]([CH3:48])[CH2:37][CH2:38][CH:39]=[C:40]([CH3:47])[CH2:41][CH2:42][CH:43]=[C:44]([CH3:46])[CH3:45])[CH2:26][P:27](=[O:28])([OH:32])[OH:30]

참가 물질

3

반응물 2

HCID 54245426Methyl 3-oxo-7,11,15-trimethylhexadeca-6,10,14-trienoateHCID 54462394Dimethyl [2-oxo-6,10,14-trimethylpentadeca-5,9,13-trienyl]phosphonate

생성물 1

HCID 54248241[2-Hydroxy-6,10,14-trimethylpentadeca-5,9,13-trienyl]phosphonic acid

실험 절차

This compound was prepared similarly by the method described in Step 2 of Example 1 except that methyl 3-oxo-7,11,15-trimethylhexadeca-6,10,14-trienoate was replaced by dimethyl [2-oxo-6,10, 14-trimethyl-pentadeca-5,9,13-trienyl]phosphonate and the product from this reaction was used in the hydrolysis step similarly to the method used in Step 2 in Example 2 to give, after lyophilization, title compound as a nearly colorless gum.

후처리

  1. customThis compound was prepared similarly by the method
  2. customthe product from this reaction was used in the hydrolysis step similarly to the method
  3. customto give

출처 및 근거

ORD 기록
ord-fc0d33c74d1d4d298a588501bf5a2486
출처 데이터셋
uspto-grants-1994_03
특허 번호
US05298655

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