2,6-Dimethoxybiphenyl → 2,4-Dimethoxy-3-phenylbenzaldehyde

HRID 488547노트

반응식

HRID 488547 반응식
[C:1]1([C:7]2[C:12]([O:13][CH3:14])=[CH:11][CH:10]=[CH:9][C:8]=2[O:15][CH3:16])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.ClC1C(OC)=C(C=CC=1OC)[CH:21]=[O:22]>>[CH3:16][O:15][C:8]1[C:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)=[C:12]([O:13][CH3:14])[CH:11]=[CH:10][C:9]=1[CH:21]=[O:22]

참가 물질

3

반응물 2

HCID 9142572,6-DimethoxybiphenylHCID 133437053-Chloro-2,4-dimethoxybenzaldehyde

생성물 1

HCID 219461432,4-Dimethoxy-3-phenylbenzaldehyde수율 95%

실험 절차

Compound 2c was synthesized from 1c in 95% yield using the procedure described for 2a. 1H NMR(acetone-d6): δ 10.28 (s, 1H), 7.88 (d, J=8.8 Hz, 1H), 7.42–7.49 (m, 5H), 7.10 (d, J=8.8 Hz, 1H), 3.89 (s, 3H), 3.48 (s, 3H).

출처 및 근거

ORD 기록
ord-12b2eb005fb74b858047853a45be5cd3
출처 데이터셋
uspto-grants-2005_12
특허 번호
US06972339B2

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