Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Glyceraldehyde → Benzyl 4,5-dihydroxy-2-pentenoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Glyceraldehyde | HCID 751 | — |
| 반응물 | (Benzyloxycarbonylmethyl)triphenylphosphonium bromide | HCID 11214019 | — |
| 용매 | 1,2-Epoxybutane | HCID 7834 | — |
| 생성물 | Benzyl 4,5-dihydroxy-2-pentenoate | HCID 54529065 | — |
반응 단계
A mixture of DL-glycerinaldehyde (4.5 g, 50 mmole) and (benzyloxycarbonylmethyl)-triphenyl-phosphoniumbromide (24.57 g, 50 mmole) in 100 ml 1,2-epoxybutane was refluxed overnight. The mixture was evaporated under vacuum and the product was isolated by silica gel column chromatography.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06974802B2 |
| 출처 데이터셋 | uspto-grants-2005_12 |
| ORD ID | ord-274a806608864003b6ffad9050318002 |
| 출처 메모 | uspto-grants-2005_12 |