Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4,4'-Dimethoxydiphenylamine → 4-Methyltriphenylamine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4,4'-Dimethoxydiphenylamine | HCID 7571 | — |
| 반응물 | Triphenylphosphine | HCID 11776 | — |
| 반응물 | 4-Iodotoluene | HCID 12207 | — |
| 반응물 | sodium 2-methylpropan-2-olate | HCID 178418730 | — |
| 용매 | O-Xylene | HCID 7237 | — |
| 생성물 | 4-Methyltriphenylamine | HCID 11299928 | — |
반응 단계
9.70 g (57.3 mmols) of N,N-diphenylamine (31a), 12.5 g (57.3 mmols) of 4-iodotoluene (32b), 6.61 g (68.8 mmols) of t-BuONa, 260 mg (1.15 mmols) of Pd(CH3COO)2 and 1.20 g (4.58 mmols) of triphenylphosphine were dissolved in xylene and refluxed in an atmosphere of nitrogen for 4 hours.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06979746B2 |
| 출처 데이터셋 | uspto-grants-2005_12 |
| ORD ID | ord-d74503ffc1d245c6b4aa61674ca5a104 |
| 출처 메모 | uspto-grants-2005_12 |