Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methanol → methyl 2-[(4,6-dimethoxytriazin-2-y1)oxy]-6-[1-(N-methoxyimino)ethyl]benzoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methanol | HCID 887 | — |
| 반응물 | Potassium Acetate | HCID 517044 | — |
| 반응물 | O-Methylhydroxylamine hydrochloride | HCID 521874 | — |
| 반응물 | Methyl 2-acetyl-6-[(4,6-dimethoxytriazin-2-yl)oxy]benzoate | HCID 19089388 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | methyl 2-[(4,6-dimethoxytriazin-2-y1)oxy]-6-[1-(N-methoxyimino)ethyl]benzoate | HCID 86747186 | 48% |
반응 단계
0.9 of methyl 2-acetyl-6-[(4,6-dimethoxytriazin-2-yl)oxy]benzoate, 0.68 g of methoxyamine hydrochloride and 0.80 g of potassium acetate were added to 30 ml of methanol, and the resultant mixture was stirred for one day and one night at room temperature. The resultant reaction liquor was poured into water, and was extracted with ethyl acetate. After washing the extracted product with water, the washed product was dried and concentrated to obtain an oily product. This was then purified by column chromatography to obtain 0.47 g of the aimed compound (melting point=131° to 135° C.) at a yield of 48%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05242895 |
| 출처 데이터셋 | uspto-grants-1993_09 |
| ORD ID | ord-9caf7f2af9b04e69903afed00c9e43d0 |
| 출처 메모 | uspto-grants-1993_09 |