Phenylphosphonic Acid → Phosphonic acid, P-phenyl-, zinc salt (1:1)

HRID 492043

반응식

HRID 492043 반응식
[C:1]1([P:7](=[O:10])([OH:9])[OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[O-2].[Zn+2:12]>O>[C:1]1([P:7](=[O:8])([O-:10])[O-:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Zn+2:12]

참가 물질

4

반응물 2

HCID 15295Phenylphosphonic AcidHCID 3007857Zinc Oxide

생성물 1

HCID 15878909Phosphonic acid, P-phenyl-, zinc salt (1:1)수율 98%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

In a glass ball mill container having a volume of 900 mL, 1000 g of 1 mmφ zirconia beads were charged, further 17.0 g (108 mmol) of phenylphosphonic acid (manufactured by Nissan Chemical industries, Ltd.), 8.78 g (108 mmol) of zinc oxide and 231 g of water were mixed, stirred at 170 rpm for 20 hours at room temperature. Then the slurry was separated from zirconia beads, and the separated slurry was filtered, and the wet cake was fully washed with water. Thereafter, the slurry was dried at 150° C. to obtain 23.4 g (yield 98%) of the aimed product as white crystal. The average particle diameter was 1.1 μm with a laser diffraction type particle size distribution meter (manufactured by Seishin Enterprise Co., Ltd., PRO-7000S).

후처리

  1. additionwere charged
  2. customThen the slurry was separated from zirconia beads
  3. filtrationthe separated slurry was filtered
  4. washthe wet cake was fully washed with water
  5. customThereafter, the slurry was dried at 150° C.

출처 및 근거

ORD 기록
ord-505303cac5f6443b8fa3eac4a29002a2
출처 데이터셋
uspto-grants-2009_05
특허 번호
US07531585B2

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