Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Camphor → Bornylene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Camphor | HCID 2537 | — |
| 반응물 | HCID 178418348 | HCID 178418348 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | Bornylene | HCID 10047 | — |
반응 단계
1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one (1-camphor) was converted into its 4-toluenesulfonylhydrazone, which was then reacted with methyllithium in ether, to give the title compound. The method used was that described by Shapiro and Duncan, Organic Synthesis, Vol 51, pp 67-69, for the conversion of racemic camphor into racemic 1,7,7-trimethylbicyclo[2.2.1]hept-2-ene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05242911 |
| 출처 데이터셋 | uspto-grants-1993_09 |
| ORD ID | ord-58c68fbf10174a44867b9854715d2022 |
| 출처 메모 | uspto-grants-1993_09 |