4-(4-propoxyphenyl)benzoic Acid → HCID 22925874, 화합물

HRID 493045노트

반응식

HRID 493045 반응식
[CH2:1]([O:4][C:5]1[CH:10]=[CH:9][C:8]([C:11]2[CH:19]=[CH:18][C:14]([C:15]([OH:17])=[O:16])=[CH:13][CH:12]=2)=[CH:7][CH:6]=1)[CH2:2][CH3:3]>S(Cl)(Cl)=O>[CH2:1]([O:4][C:5]1[CH:6]=[CH:7][C:8]([C:11]2[CH:19]=[CH:18][C:14]([C:15]([O:17][C:8]([CH3:11])([CH3:9])[CH3:7])=[O:16])=[CH:13][CH:12]=2)=[CH:9][CH:10]=1)[CH2:2][CH3:3]

참가 물질

3

반응물 1

HCID 20636134-(4-propoxyphenyl)benzoic Acid

생성물 1

HCID 22925874HCID 22925874, 화합물

시약·촉매·용매 1

HCID 24386Thionyl Chloride용매

실험 절차

Thionyl chloride (10 ml) was added to 5.0 g (19.5 mmol) of 4-(4-n-propyloxyphenyl)benzoic acid synthesized in the step (ii), and the mixture was refluxed overnight. After an excess amount of thionyl chloride was removed from the resultant mixture, 4′-(n-propyloxy)-4-(tert-butoxycarbonyl)biphenyl was obtained in the same manner as in the Example 104.

후처리

  1. customsynthesized in the step (ii)
  2. temperaturethe mixture was refluxed overnight
  3. customAfter an excess amount of thionyl chloride was removed from the resultant mixture

출처 및 근거

ORD 기록
ord-53786bc9e3f642faa0c790f2397e53ac
출처 데이터셋
uspto-grants-2009_05
특허 번호
US07534547B2

반응 노트

불러오는 중…