Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethyl diazoacetate → Ethyl 2-(benzyloxymethyl)cyclopropanecarboxylate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethyl diazoacetate | HCID 12192 | — |
| 반응물 | Allyl benzyl ether | HCID 84542 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | Ethyl 2-(benzyloxymethyl)cyclopropanecarboxylate | HCID 22325150 | — |
반응 단계
31.2 g of ethyl diazoacetate are added to a solution of 0.3 mol of allyl benzyl ether in 150 ml of ether with the aid of a push-syringe. After stirring for 16 hours, 31.2 g of ethyl diazoacetate are added again. After 24 hours the mixture is filtered. The organic phase is washed with saturated NaHCO3 solution and then treated in customary manner. Chromatography over silica gel (dichloromethane) allows the expected product to be obtained.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06943184B2 |
| 출처 데이터셋 | uspto-grants-2005_09 |
| ORD ID | ord-c809cba580fc45cd9cee4bfaa41681aa |
| 출처 메모 | uspto-grants-2005_09 |