참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Bicyclo(2.2.1)heptane-2-methanol | HCID 21308 | — |
| 반응물 | HCID 178418287 | HCID 178418287 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | Bicyclo[2.2.1]heptane-2-carbaldehyde | HCID 86864 | 42% |
반응 단계
A stirred suspension of 2-norbornylmethanol (0.5 ml; 5.8 mmol) and PCC on Al2O3* in CH2Cl2 (25 ml) was stirred at 2-3° C. for 1 h and allowed to slowly warm up to rt. The reaction mixture was filtered and the solid material washed with CH2Cl2 (2×25 ml). The combined organic fractions were adsorbed onto silica and chromatographed to give 300 mg (42%) product as an oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06943159B1 |
|---|
| 출처 데이터셋 | uspto-grants-2005_09 |
|---|
| ORD ID | ord-99da1fecffe54b5291694c2e35173483 |
|---|
| 출처 메모 | uspto-grants-2005_09 |
|---|
