Toluene → Dicyclopentadiene

HRID 50132

반응식

[C:1]([O-])(=O)[CH:2]=[CH2:3].C1CC=CC=1.[C:11]1([CH3:17])[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>>[CH2:2]1[CH:1]2[CH:14]3[CH:13]=[CH:12][CH:16]([CH:11]2[CH:17]=[CH:3]1)[CH2:15]3

참가 물질

반응물 3

HCID 1140Toluene

HCID 7612Cyclopentadiene

HCID 25188Acrylate

생성물 1

HCID 6492Dicyclopentadiene

실험 절차

The derivative was synthesized as follows. 20 grams of the derivative of acrylate obtained as the third example was dissolved in 20 milliliters of toluene. 7 grams of cyclopentadiene was dropped into the solution cooled with ice, and was agitated through all night. Dicyclopentadiene was produced as by-product, and was eliminated in vacuum. Then, 24.9 grams of the derivative of norbornene was obtained. The derivative of norbornene was viscous liquid, and the yield was 95%.

후처리

customThe derivative was synthesized
temperaturecooled with ice

출처 및 근거

ORD 기록: ord-ed221a40b0554bbd900e864b34ebf7eb
출처 데이터셋: uspto-grants-2004_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06710188B2

연결된 노트

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