Chlorotrimethylsilane → Stannane, chlorotricyclohexyl-

HRID 501918

반응식

HRID 501918 반응식
C[Si]([Cl:5])(C)C.[OH-].[CH:7]1([Sn+:13]([CH:20]2[CH2:25][CH2:24][CH2:23][CH2:22][CH2:21]2)[CH:14]2[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]2)[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1>>[CH:20]1([Sn:13]([Cl:5])([CH:7]2[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]2)[CH:14]2[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]2)[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25]1

참가 물질

3

반응물 2

HCID 6397ChlorotrimethylsilaneHCID 9864905Cyhexatin

생성물 1

HCID 76539Stannane, chlorotricyclohexyl-

실험 절차

In a 500 mL three-necked flask, trimethylsilyl chloride (170 g, 109 mmol) was added to tricyclohexyltin hydroxide (80 g, 133 mmol) and heated at reflux during 18 hours. After distillation of trimethylsilyl chloride in excess and hexamethyldisiloxane under reduced pressure, the crude product was recrystallized in petroleum ether. White needles were obtained (39.82 g, 79.6 mmol).

후처리

  1. temperatureheated
  2. temperatureat reflux during 18 hours
  3. distillationAfter distillation of trimethylsilyl chloride in excess and hexamethyldisiloxane under reduced pressure
  4. customthe crude product was recrystallized in petroleum ether
  5. customWhite needles were obtained (39.82 g, 79.6 mmol)

출처 및 근거

ORD 기록
ord-93315c5e7b7e4903937b9806282aec0b
출처 데이터셋
uspto-grants-2010_08
특허 번호
US07772417B2

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