3-Ethynylthiophene → 1-Chloro-4-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranos-1-yl)-2-[4-(thiophen-3-yl-ethynyl)-benzyl]-benzene

HRID 502101

반응식

HRID 502101 반응식
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([C@:8]2([O:26][C@H:25]([CH2:27][O:28][C:29](=[O:31])[CH3:30])[C@@H:20]([O:21][C:22](=[O:24])[CH3:23])[C@H:15]([O:16][C:17](=[O:19])[CH3:18])[C@H:10]2[O:11][C:12](=[O:14])[CH3:13])[OH:9])=[CH:4][C:3]=1[CH2:32][C:33]1[CH:38]=[CH:37][C:36](OS(C(F)(F)F)(=O)=O)=[CH:35][CH:34]=1.[C:47]([C:49]1[CH:53]=[CH:52][S:51][CH:50]=1)#[CH:48]>>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([C@:8]2([O:26][C@H:25]([CH2:27][O:28][C:29](=[O:31])[CH3:30])[C@@H:20]([O:21][C:22](=[O:24])[CH3:23])[C@H:15]([O:16][C:17](=[O:19])[CH3:18])[C@H:10]2[O:11][C:12](=[O:14])[CH3:13])[OH:9])=[CH:4][C:3]=1[CH2:32][C:33]1[CH:38]=[CH:37][C:36]([C:48]#[C:47][C:49]2[CH:53]=[CH:52][S:51][CH:50]=2)=[CH:35][CH:34]=1

참가 물질

3

반응물 2

HCID 35484223-EthynylthiopheneHCID 866059781-chloro-4-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranos-1-yl)-2-(4-trifluoromethylsulfonyloxy-benzyl)-benzene

생성물 1

HCID 866072521-Chloro-4-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranos-1-yl)-2-[4-(thiophen-3-yl-ethynyl)-benzyl]-benzene

실험 절차

The compound was obtained starting from 1-chloro-4-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranos-1-yl)-2-(4-trifluoromethylsulfonyloxy-benzyl)-benzene and 3-ethynyl-thiophene.

후처리

  1. customThe compound was obtained

출처 및 근거

ORD 기록
ord-342aa5d16c244232a73c569ca9b81be4
출처 데이터셋
uspto-grants-2010_08
특허 번호
US07772378B2

연결된 노트

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