Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sulfuric Acid → 1,3,5-Triazine, 2-chloro-4,6-bis(2,4-dimethylphenyl)-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sulfuric Acid | HCID 1118 | — |
| 반응물 | M-Xylene | HCID 7929 | — |
| 반응물 | Cyanuric chloride | HCID 7954 | — |
| 반응물 | Aluminum(III) Chloride | HCID 6451240 | — |
| 용매 | Chlorobenzene | HCID 7964 | — |
| 생성물 | 1,3,5-Triazine, 2-chloro-4,6-bis(2,4-dimethylphenyl)- | HCID 71059 | — |
| 생성물 | 2,4,6-Tris(2,4-dimethylphenyl)-1,3,5-triazine | HCID 22475988 | — |
반응 단계
To a stirring mixture of 1 eq of cyanuric chloride, 3 eq of AlCl3 in chlorobenzene, was added 0.24 eq of concentrated H2SO4 at ice-bath temperature. After 5 min of stirring 2 eq of m-xylene was added. After another 5 min, the cooling bath was removed and the reaction mixture was stirred at room temperature. HPLC analysis after 2 h at room temperature showed 100% of the cyanuric chloride had reacted to give 2-chloro-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine and 2,4,6-tris(2,4-dimethylphenyl)-1,3,5-triazine, which were present in a ratio of 86:14.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06710177B2 |
| 출처 데이터셋 | uspto-grants-2004_03 |
| ORD ID | ord-b5368d3525d64045b8a724b3abbc8513 |
| 출처 메모 | uspto-grants-2004_03 |