반응식
[CH2:1]1[CH:5]2[C@@H:6]3C=C[C@H]([CH:4]2C=[CH:2]1)C3.[CH3:11][O:12][C:13](=[O:16])[CH:14]=[CH2:15].C1(C=CC(O)=CC=1)O>>[CH3:11][O:12][C:13]([CH:14]1[CH2:4][CH:5]2[CH2:6][CH:15]1[CH:2]=[CH:1]2)=[O:16]참가 물질
4
반응 조건
- 온도
- 220 °C
실험 절차
DCPD (dicyclopentadiene, Aldrich, 256.5 ml, 1.9 mol), methylacrylate (Aldrich, 405 ml, 4.5 mol) and hydroquinone (3.2 g, 0.03 mol) were charged into a 2 L high-pressure autoclave, and the temperature was raised to 220° C. The resulting mixture was reacted for 5 hours with stirring at 300 rpm. After the reaction was completed, the reaction mixture was cooled and transferred to a distilling apparatus. The reaction mixture was distilled under a reduced pressure (1 torr) using a vacuum pump to yield the title compound at 50° C. (yield: 57.6%, exo/endo=58/42).
후처리
- customThe resulting mixture was reacted for 5 hours
- temperaturethe reaction mixture was cooled
- distillationThe reaction mixture was distilled under a reduced pressure (1 torr)
출처 및 근거
- ORD 기록
- ord-0a7e305da0914c118f2e93d43a9b3d2c
- 출처 데이터셋
- uspto-grants-2010_08
- 특허 번호
- US07786230B2
연결된 노트
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