Methanol → (N-(p-nitrophenylsulfonyl)imino)phenyliodinane

HRID 510779

반응식

HRID 510779 반응식
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10]([NH2:13])(=[O:12])=[O:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].[OH-].[K+].[C:16](O)(=O)[CH3:17].[C:20](O)(=O)[CH3:21].[I:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1.[CH3:31]O>>[N+:1]([C:4]1[CH:5]=[CH:6][C:7]([S:10]([N:13]=[C:17]2[CH2:16][CH2:21][CH2:20][CH2:31][I:24]2[C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)(=[O:11])=[O:12])=[CH:8][CH:9]=1)([O-:3])=[O:2]

참가 물질

5

반응물 4

HCID 887MethanolHCID 14797Potassium HydroxideHCID 227844-NitrobenzenesulfonamideHCID 12217721Iodo benzene diacetate

생성물 1

HCID 86651740(N-(p-nitrophenylsulfonyl)imino)phenyliodinane수율 78.1%

실험 절차

To a solution of 4-nitrobenzenesulfonamide (0.628 g, 3.10 mmol) and potassium hydroxide (0.410 g, 6.21 mmol) in MeOH (10 ml) at 0° C. was added iodobenzene diacetate (1.00 g, 3.10 mmol), and the reaction was allowed to warm to ambient temperature and stir for 4 hours. The reaction was filtered, and the solids were washed with water and dried under reduced pressure to yield 980 mg of the title compound (78.1% yield).

후처리

  1. filtrationThe reaction was filtered
  2. washthe solids were washed with water
  3. customdried under reduced pressure

출처 및 근거

ORD 기록
ord-d1db43b5f07e46dda8d4ba0bb8f5207f
출처 데이터셋
uspto-grants-2015_08
특허 번호
US09096567B2

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