Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methyl fluorosulfate → (2S)-1,1-Dimethyl-2-(4-methoxybenzylthiomethyl)pyrrolidinium fluorosulfonate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methyl fluorosulfate | HCID 9870 | — |
| 반응물 | (2S)-2-(4-Methoxybenzylthiomethyl)-1-methylpyrrolidine | HCID 57048351 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | (2S)-1,1-Dimethyl-2-(4-methoxybenzylthiomethyl)pyrrolidinium fluorosulfonate | HCID 14880299 | — |
반응 단계
The procedure described in Preparation 5-(5) was repeated, but using 740 mg of (2S)-2-(4-methoxybenzylthiomethyl)-1-methylpyrrolidine and 243 μl of methyl fluorosulfonate in the presence of 22 ml of methylene chloride, to afford 1.0 g of the title compound as crystals, melting at 150°-153° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05242914 |
| 출처 데이터셋 | uspto-grants-1993_09 |
| ORD ID | ord-5a0095e69f164f00815bcbd1c99cbbde |
| 출처 메모 | uspto-grants-1993_09 |