Thionyl Chloride → HCID 86675009, 화합물
반응식
[CH2:1]([O:3][C:4]([O:6][C:7]1[CH:15]=[CH:14][CH:13]=[CH:12][C:8]=1[C:9](O)=[O:10])=[O:5])[CH3:2].S(Cl)([Cl:18])=O>C1(C)C=CC=CC=1.N1C=CC=CC=1>[CH2:1]([O:3][C:4]([O:6][C:7]1[CH:15]=[CH:14][CH:13]=[CH:12][C:8]=1[C:9]([Cl:18])=[O:10])=[O:5])[CH3:2]참가 물질
5
실험 절차
5.9 g (28 mmol) of 2-(ethoxycarbonyloxy)benzoic acid are dissolved in 30 ml of toluene with a few drops of pyridine. 2.15 ml (29 mmol) of thionyl chloride are added dropwise and the mixture is stirred at ambient temperature for 18 h and then concentrated to dryness. The residue is precipitated from pentane. The solid is filtered off and then dried. 5.2 g of 2-(ethoxycarbonyloxy)benzoyl chloride are obtained in the form of a white solid with a yield of 80%.
후처리
- concentrationconcentrated to dryness
- customThe residue is precipitated from pentane
- filtrationThe solid is filtered off
- customdried
출처 및 근거
- ORD 기록
- ord-2448078ef1654767975a0b7b083fd44c
- 출처 데이터셋
- uspto-grants-2015_08
- 특허 번호
- US09102607B2
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