Manganese(2+) dichloride → 1,8-diethyl-1,4,8,11-tetraazacyclotetradecane manganese(II) dichloride

HRID 513982노트

반응식

HRID 513982 반응식
[Cl-:1].[Mn+2:2].[Cl-].[CH2:4]([N:6]1[CH2:19][CH2:18][CH2:17][NH:16][CH2:15][CH2:14][N:13]([CH2:20][CH3:21])[CH2:12][CH2:11][CH2:10][NH:9][CH2:8][CH2:7]1)[CH3:5]>CC(N(C)C)=O>[Cl-:1].[Cl-:1].[Mn+2:2].[CH2:4]([N:6]1[CH2:19][CH2:18][CH2:17][NH:16][CH2:15][CH2:14][N:13]([CH2:20][CH3:21])[CH2:12][CH2:11][CH2:10][NH:9][CH2:8][CH2:7]1)[CH3:5]

참가 물질

4

반응물 2

HCID 10313134Manganese(2+) dichlorideHCID 184516951,8-Diethyl-1,4,8,11-tetraazacyclotetradecane

생성물 1

HCID 666083811,8-diethyl-1,4,8,11-tetraazacyclotetradecane manganese(II) dichloride수율 97%

시약·촉매·용매 1

HCID 31374Dimethylacetamide용매

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온도
100 °C

실험 절차

12.6 g (0.1 mol) of manganese(II) chloride were dissolved in 100 ml of DMAC. The solution was admixed with 25.6 g (0.1 mol) of 1,8-diethyl-1,4,8,11-tetraazacyclotetradecane. The reaction mixture was heated at 100° C. for 5 hours. The resulting suspension was then cooled to room temperature, and the resulting solid was filtered off, washed with 50 ml of DMAC and then dried in vacuo at a temperature of 80° C. This gave 37.1 g of the pale grey complex, which corresponds to a yield of 97.0%.

후처리

  1. temperatureThe resulting suspension was then cooled to room temperature
  2. filtrationthe resulting solid was filtered off
  3. washwashed with 50 ml of DMAC
  4. customdried in vacuo at a temperature of 80° C

출처 및 근거

ORD 기록
ord-0c560bd7617d4406979dc099f6945af5
출처 데이터셋
uspto-grants-2015_08
특허 번호
US09102903B2

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