반응식
CO[CH2:3][C:4]([OH:6])=[O:5].[CH2:7]([OH:13])[CH2:8][CH2:9][CH2:10]CC.[CH3:14]O>>[OH:13][CH2:7][CH2:8][CH2:9][CH2:10][CH2:3][C:4]([O:6][CH3:14])=[O:5]참가 물질
반응 조건
- 온도
- 300 °C
실험 절차
Nylon 6 (0.1 g), methoxyacetic acid as a carboxylic acid (0.45 g) and methanol (3.0 g) were added to a 10 mL volume reactor equipped with a tube (outer diameter: ⅜ inches, inner diameter: 7.53 mm, length: 23 cm), nitrogen substitution was conducted at room temperature, and the reactor was sealed. The reactor was put into an electric furnace heated to 300° C. (pressure: 16.3 MPa), and the change over time was measured. In the measurement, the obtained reaction mixture and 1-hexanol as an internal standard substance were weighed and used as analysis samples for a gas chromatography analysis. An integral value was calculated by a gas chromatography analysis, and a table of a standard curve was prepared and the yield of methyl 6-hydroxycaproate was obtained therefrom. The result is shown in Table 3.
후처리
- customequipped with a tube (outer diameter: ⅜ inches, inner diameter: 7.53 mm, length: 23 cm), nitrogen substitution
- customwas conducted at room temperature
- customthe reactor was sealed
- customa table of a standard curve was prepared
출처 및 근거
- ORD 기록
- ord-e3735121d0734024a049f8d9bec28311
- 출처 데이터셋
- uspto-grants-2015_08
- 특허 번호
- US09115075B2
연결된 노트
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