Potassium Carbonate → HCID 22568938, 화합물

HRID 51753노트

반응식

HRID 51753 반응식
[CH2:1]([O:3][C:4]1([C:7]2[CH:12]=[CH:11][C:10]([C:13]#[C:14][Si](C)(C)C)=[CH:9][C:8]=2[CH:19]([CH3:21])[CH3:20])[CH2:6][CH2:5]1)[CH3:2].C(=O)([O-])[O-].[K+].[K+]>CO>[CH2:1]([O:3][C:4]1([C:7]2[CH:12]=[CH:11][C:10]([C:13]#[CH:14])=[CH:9][C:8]=2[CH:19]([CH3:20])[CH3:21])[CH2:6][CH2:5]1)[CH3:2]

참가 물질

4

반응물 2

HCID 11430Potassium CarbonateHCID 22569012[4-(1-Ethoxycyclopropyl)-3-isopropyl-phenylethynyl]-trimethylsilane2회

생성물 1

HCID 22568938HCID 22568938, 화합물

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

Using General Procedure E; [4-(1-ethoxycyclopropyl)-3-isopropyl-phenylethynyl]-trimethylsilane (Intermediate 102, 210.0 mg, 0.70 mmol) in methanol (10 mL) was treated with potassium carbonate (100.0 mg, 0.72 mmol) and stirred overnight at ambient temperature. The crude alkyne was used directly in the next reaction.

출처 및 근거

ORD 기록
ord-99479748991d4d5784f9d47d803d59d6
출처 데이터셋
uspto-grants-2004_03
특허 번호
US06713647B2

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