Potassium Carbonate → Ethyl 4-(benzyloxy)-3-hydroxybenzoate

HRID 521518노트

반응식

HRID 521518 반응식
[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([O:19]C(=O)C)[CH:6]=1)[CH3:2].C(=O)([O-])[O-].[K+].[K+]>CO>[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([OH:19])[CH:6]=1)[CH3:2]

참가 물질

4

반응물 2

HCID 11430Potassium CarbonateHCID 67170201HCID 67170201, 화합물

생성물 1

HCID 11311797Ethyl 4-(benzyloxy)-3-hydroxybenzoate

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

The compound of step 1 (10 g, 31.8 mmol) was dissolved in methanol, potassium carbonate (88 mg, 0.636 mmol) was added and the mixture was stirred for 2 h under reflux. After evaporation to dryness, the residue was used without further purification in the subsequent step.

후처리

  1. temperatureunder reflux
  2. customAfter evaporation to dryness
  3. customthe residue was used without further purification in the subsequent step

출처 및 근거

ORD 기록
ord-dfacff06dd0949c28dda9c235b25f569
출처 데이터셋
uspto-grants-2016_05
특허 번호
US09328071B2

반응 노트

불러오는 중…