Diethyl Ether → Silver isobutyrylacetate

HRID 522242노트

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HRID 522242 반응식
N(CCO)CCO.CCOCC.[C:13]([CH2:18][C:19]([OH:21])=[O:20])(=[O:17])[CH:14]([CH3:16])[CH3:15].[N+]([O-])([O-])=O.[Ag+:26]>O>[C:13]([CH2:18][C:19]([O-:21])=[O:20])(=[O:17])[CH:14]([CH3:16])[CH3:15].[Ag+:26]

참가 물질

6

반응물 4

HCID 3283Diethyl EtherHCID 8113DiethanolamineHCID 24470Silver NitrateHCID 4400244-Methyl-3-oxopentanoic acid

생성물 1

HCID 86633510Silver isobutyrylacetate

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
15 °C

실험 절차

Diethanolamine (0.33 g) was dissolved in water (5 ml) and an ether solution (10 ml) containing the isobutyrylacetic acid (0.43 g) was added thereto. Next, while stirring the obtained mixture at 15° C., an aqueous solution (5 ml) containing silver nitrate (0.51 g) was added dropwise thereto and further stirred for 15 minutes. The precipitated white precipitate was filtered out, thereby obtaining silver isobutyrylacetate (yield: 0.37 g).

후처리

  1. additionwas added
  2. additionwas added dropwise
  3. stirringfurther stirred for 15 minutes
  4. filtrationThe precipitated white precipitate was filtered out

출처 및 근거

ORD 기록
ord-e2060289d04048dd9bf1027b7f211717
출처 데이터셋
uspto-grants-2016_05
특허 번호
US09328254B2

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