Diethyl Ether → Silver benzoylacetate

HRID 522244노트

반응식

HRID 522244 반응식
N(CCO)CCO.CCOCC.[C:13]([CH2:21][C:22]([OH:24])=[O:23])(=[O:20])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[N+]([O-])([O-])=O.[Ag+:29]>O>[C:13]([CH2:21][C:22]([O-:24])=[O:23])(=[O:20])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[Ag+:29]

참가 물질

6

반응물 4

HCID 3283Diethyl EtherHCID 8113DiethanolamineHCID 24470Silver NitrateHCID 97045Benzoylacetic acid

생성물 1

HCID 86633512Silver benzoylacetate

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
15 °C

실험 절차

Diethanolamine (0.33 g) was dissolved in water (5 ml) and an ether solution (20 ml) containing the benzoylacetic acid (0.54 g) was added thereto. Next, while stirring the obtained mixture at 15° C., a solution (5 ml) containing silver nitrate (0.51 g) was added dropwise thereto and further stirred for 15 minutes. The precipitated light-yellow precipitate was filtered out, thereby obtaining silver benzoylacetate (yield: 0.79 g).

후처리

  1. additionwas added
  2. additionwas added dropwise
  3. stirringfurther stirred for 15 minutes
  4. filtrationThe precipitated light-yellow precipitate was filtered out

출처 및 근거

ORD 기록
ord-4129df256e344cf680fae1f094ca25ec
출처 데이터셋
uspto-grants-2016_05
특허 번호
US09328254B2

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