참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Allyl chloride | HCID 7850 | — |
| 반응물 | Triethoxysilane | HCID 13830 | — |
| 촉매 | Chloro(1,5-cyclooctadiene)iridium(I) dimer | HCID 6436381 | — |
| 용매 | P-Xylene | HCID 7809 | — |
| 생성물 | (3-Chloropropyl)triethoxysilane | HCID 78771 | 83% |
반응 단계
In a minilab pressure reactor of the TINYCLAVE type (BUECHI) with a capacity of 25 ml, 4 g of p-xylene, 4.2 g (0. 055 mol) of allyl chloride and 8.2 g (0.05 mol) of triethoxysilane were mixed intensively with 0.16 mg (10-3 mol %) of chloro-(1,5-cyclooctadiene)iridium(I) dimer at room temperature for one hour. The reaction mixture was then heated at 80° C. for 2 hours in a thermostat. Analysis by gas chromatography gave a product yield of 83% of 3-chloropropyltriethoxysilane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05616762 |
|---|
| 출처 데이터셋 | uspto-grants-1997_04 |
|---|
| ORD ID | ord-f4cb1ec4b0a1458a99cc43273097e972 |
|---|
| 출처 메모 | uspto-grants-1997_04 |
|---|
