Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Allyl chloride → (3-Chloropropyl)triethoxysilane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Allyl chloride | HCID 7850 | — |
| 반응물 | Triethoxysilane | HCID 13830 | — |
| 촉매 | Chloro(1,5-cyclooctadiene)iridium(I) dimer | HCID 6436381 | — |
| 용매 | P-Xylene | HCID 7809 | — |
| 생성물 | (3-Chloropropyl)triethoxysilane | HCID 78771 | 61% |
반응 단계
In analogy to Example 3, a homogeneous reaction solution of 4 g of p-xylene, 3.8 g (0.05 mol) of allyl chloride (instead of 4.2 g corresponding to 0.055 mol), 8.2 g (0.05 mol) of triethoxysilane and 0.16 mg (10-3 mol %) of chloro-(1,5-cyclooctadiene)iridium(I) dimer were reacted without a relatively long mixing or storage time. Analysis by gas chromatography gave a product yield of only 61% of 3-chloropropyltriethoxysilane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05616762 |
| 출처 데이터셋 | uspto-grants-1997_04 |
| ORD ID | ord-1046655f81d5414dad9edc05ddc70660 |
| 출처 메모 | uspto-grants-1997_04 |