3,3,3-Trifluoropropene → 3,3,3-Trifluoropropylcyclopentyldiethoxysilane
반응식
[F:1][C:2]([F:6])([F:5])[CH:3]=[CH2:4].[CH:7]1([SiH:12]([O:16][CH2:17][CH3:18])[O:13][CH2:14][CH3:15])[CH2:11][CH2:10][CH2:9][CH2:8]1>O.[Ir](Cl)(Cl)Cl.CC1C=CC(C)=CC=1>[F:1][C:2]([F:6])([F:5])[CH2:3][CH2:4][Si:12]([CH:7]1[CH2:8][CH2:9][CH2:10][CH2:11]1)([O:16][CH2:17][CH3:18])[O:13][CH2:14][CH3:15]참가 물질
5
실험 절차
In analogy to Example 3, a mixture of 3 g of p-xylene, 5.3 g (0.055 mol) of 3,3,3-trifluoro-1-propene and 9.4 g (0.5 mol) of cyclopentyldiethoxysilane was reacted in the presence of 0.1 mg of iridium(III) chloride hydrate, after a mixing time of 70 minutes, at 83° C. over 180 minutes. Analysis by gas chromatography gave a product yield of 77% of 3,3,3-trifluoropropylcyclopentyldiethoxysilane.
출처 및 근거
- ORD 기록
- ord-844fb9cc8acf4c52b30fdadb2a3243f0
- 출처 데이터셋
- uspto-grants-1997_04
- 특허 번호
- US05616762
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