Chloro(diphenyl)silane → Benzyl 5-(chlorodiphenylsilyl)pentanoate

HRID 530135

반응식

HRID 530135 반응식
[Cl:1][SiH:2]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:15]([O:21][CH2:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)(=[O:20])[CH2:16][CH2:17][CH:18]=[CH2:19]>>[Cl:1][Si:2]([C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1)([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1)[CH2:19][CH2:18][CH2:17][CH2:16][C:15]([O:21][CH2:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)=[O:20]

참가 물질

3

반응물 2

HCID 74206Chloro(diphenyl)silaneHCID 100520354-Pentenoic acid, phenylmethyl ester

생성물 1

HCID 90418864Benzyl 5-(chlorodiphenylsilyl)pentanoate

반응 조건

온도
60 °C

실험 절차

To a mixture of chlorodiphenylsilane (0.49 g; 2.58 mmol) and benzyl pent-4-enoate (0.50 g; 2.58 mmol) under argon was added two drops of Karstedt's catalyst solution (in xylenes; ˜2% Pt). The reaction vessel was sealed and the mixture was heated to 60° C. for 15 hours. The crude liquid was used without purification.

후처리

  1. customThe reaction vessel was sealed
  2. customThe crude liquid was used without purification

출처 및 근거

ORD 기록
ord-6cd526816cce4681ae3f154cca16a097
출처 데이터셋
uspto-grants-2016_05
특허 번호
US09352049B2

연결된 노트

불러오는 중…