Sulfamic Acid → Bis(chlorosulfonyl)amine

HRID 530178노트

반응식

HRID 530178 반응식
S(Cl)([Cl:3])=O.[S:5](=[O:9])(=O)([OH:7])[NH2:6].[Cl:10][S:11]([OH:14])(=O)=[O:12]>>[NH:6]([S:5]([Cl:3])(=[O:9])=[O:7])[S:11]([Cl:10])(=[O:14])=[O:12]

참가 물질

4

반응물 3

HCID 5987Sulfamic Acid2회HCID 24386Thionyl Chloride2회HCID 24638Chlorosulfonic acid2회

생성물 1

HCID 9837260Bis(chlorosulfonyl)amine

실험 절차

In the above embodiments, thionyl chloride (SOCl2), sulphamic acid (NH2—SO2OH) and chlorosulphonic acid (HSO3Cl) were mixed to allow the reaction to proceed in the first step. However, these reactants may be mixed stepwise. For example, sulphamic acid (NH2—SO2OH) is first mixed with thionyl chloride (SOCl2). After the sufficient reaction of the compounds is carried out, chlorosulphonic acid (HSO3Cl) is mixed thereto and subjected to heating. According to this procedure, the desired product of the first step, HN(SO2Cl)2 can also be obtained.

후처리

  1. customthe reaction
  2. additionHowever, these reactants may be mixed stepwise
  3. customAfter the sufficient reaction of the compounds
  4. temperatureto heating

출처 및 근거

ORD 기록
ord-32a10486889a46008d35e41d2bd19885
출처 데이터셋
uspto-grants-2016_05
특허 번호
US09352966B2

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