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Water → HCID 15287832, 화합물

HRID 53240
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HRID 53240 반응식
ClC1C=C(C=CC=1)C(OO)=[O:6].[CH3:12][C:13]1[CH2:18][CH2:17][CH2:16][C:15]([CH3:20])([CH3:19])[C:14]=1/[CH:21]=[CH:22]/[C:23]#[C:24]C1C=NC=C(C=1)C(OCC)=O.Cl[C:37]1([CH:47]=[CH:46][CH:45]=[N:44][CH2:43]1)[C:38]([O:40][CH2:41][CH3:42])=[O:39].O>C(OCC)C>[O:6]1[C:13]2([CH3:12])[CH2:18][CH2:17][CH2:16][C:15]([CH3:20])([CH3:19])[C:14]12/[CH:21]=[CH:22]/[C:23]#[C:24][C:45]1[CH:46]=[CH:47][C:37]([C:38]([O:40][CH2:41][CH3:42])=[O:39])=[CH:43][N:44]=1
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 4

HCID 962WaterHCID 70297m-Chloroperbenzoic acidHCID 19962209ethyl 5-[(3E)-4-(2,6,6-trimethyl-1-cyclohexenyl)but-3-en-1-ynyl)nicotinateHCID 19962210Ethyl 3-chloronicotinate

생성물 1

HCID 15287832HCID 15287832, 화합물

시약·촉매·용매 1

HCID 3283Diethyl Ether
용매

실험 절차

0.106 g (0.310 mmol) of 50% meta-chloroperoxybenzoic acid (MCPBA) was added to a solution of 0.1 g (0.310 mmol) of ethyl 5-[(3E)-4-(2,6,6-trimethyl-1-cyclohexenyl)but-3-en-1-ynyl)nicotinate (used as a mixture with 0.6 g (0.310 mmol) of ethyl 3-chloronicotinate), in 10 mL of anhydrous diethyl ether under argon was stirred at ambient temperature for 18 hours. The solution was treated with 10 mL of water and extracted with 3×50 mL ether.

후처리

  1. extractionextracted with 3×50 mL ether

출처 및 근거

ORD 기록
ord-376d72dc83164375b08a72d01aa6d0d2
출처 데이터셋
uspto-grants-1997_04
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US05618836

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