(3-Bromophenyl)acetic acid → Ethyl 3-(bromophenyl)acetate

반응식

Br[C:2]1[CH:7]=[CH:6][C:5]([CH2:8][C:9]([O:11][CH2:12][CH3:13])=[O:10])=[CH:4][CH:3]=1.[Br:14]C1C=C(CC(O)=O)C=CC=1>>[Br:14][C:3]1[CH:4]=[C:5]([CH2:8][C:9]([O:11][CH2:12][CH3:13])=[O:10])[CH:6]=[CH:7][CH:2]=1

참가 물질

반응물 2

HCID 74653(3-Bromophenyl)acetic acid

HCID 7020609Ethyl 2-(4-bromophenyl)acetate2회

생성물 1

HCID 11470552Ethyl 3-(bromophenyl)acetate

실험 절차

Employing the same general procedure as for the preparation of ethyl (4-bromophenyl)acetate (Compound A), 100 g (463 mmol) of 3-bromophenylacetic acid was converted into the title compound (yellow oil) using 2 g of conc. H2SO4 and 500 ml of ethanol.

출처 및 근거

ORD 기록: ord-55377aaf0cc146dfad2fb4f30a07c2d6
출처 데이터셋: uspto-grants-1997_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05618943

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