Perhydroxyl radical → Oxiranemethanol, 3-methyl-3-(4-methyl-3-pentenyl)-

반응식

[O-:1]O.[OH:3][CH2:4]/[CH:5]=[C:6](/[CH3:13])\[CH2:7][CH2:8][CH:9]=[C:10]([CH3:12])[CH3:11]>>[OH:3][CH2:4][CH:5]1[O:1][C:6]1([CH3:13])[CH2:7][CH2:8][CH:9]=[C:10]([CH3:12])[CH3:11]

참가 물질

반응물 2

HCID 18500Perhydroxyl radical

HCID 643820Nerol

생성물 1

HCID 530403Oxiranemethanol, 3-methyl-3-(4-methyl-3-pentenyl)-

실험 절차

The hydroperoxide resulting from nerol can be reduced to the corresponding hydroxyl compound and this can then be cyclized with acid catalysis to give nerol oxide.

출처 및 근거

ORD 기록: ord-8e9fb367a1f3464b80c238386c6849bf
출처 데이터셋: uspto-grants-1997_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05620569

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